[Abstract] 

To develop a CO₂-free process for recovering Fe and Zn metals from electric arc furnace (EAF) dust, this study investigated the molten oxide electrolysis of various Fe₂O₃–ZnO mixtures in a B₂O₃–Na₂O electrolyte. Electrolysis was conducted using an Fe cathode and Pt anode at 1173 K by applying cell voltages that were determined based on thermodynamic calculations and cyclic voltammetry measurements. When electrolysis was conducted at a cell voltage of 1.1 V, the selective reduction of Fe oxide to Fe metal was observed without ZnO reduction. However, when 1.6 V was applied, the co-reduction of Fe oxide and ZnO to the Fe–Zn alloy was observed. In the vacuum distillation of the Fe–Zn alloy at 1000–1200 K, Zn metal with a purity of ≥99.996% was obtained with a recovery efficiency of ≥99.9%, under certain conditions. This study demonstrates the feasibility of recovering Fe and Zn from EAF dust using low-temperature molten oxide electrolysis and subsequent vacuum distillation.